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Title

Do peptide nucleic acids form self-assembled monolayers on pyrite surfaces?

AuthorsMateo-Martí, Eva CSIC ORCID; Rogero, Celia CSIC ORCID; Briones, Carlos CSIC ORCID; Martín-Gago, José A. CSIC ORCID
KeywordsPeptide nucleic acid
Gold
Pyrite
X-ray photoemission spectroscopy
X-ray absorption near-edge spectroscopy
Issue Date18-Apr-2007
PublisherElsevier
CitationSurface Science 601(18): 4195-4199 (2007)
AbstractWe have characterized the adsorption of thiol-modified peptide nucleic acid (PNA) molecules on a natural pyrite surface by means of X-ray photoelectron spectroscopy (XPS) and X-ray absorption near-edge spectroscopy (XANES) techniques. Whereas single stranded PNA forms partially-ordered self-assembled monolayers (SAMs) on gold surfaces, no preferential orientation of PNA is observed upon adsorption on pyrite (FeS2) surfaces. The N1(s) XPS core level peak of PNA has been decomposed in curve-components, and every component has been assigned to different chemical species. This analysis shows that in pyrite the PNA nucleobases interact with the iron from the surface rather than by the sulfur of the thiolated molecule.
Description5 pages, 3 figures, 1 table.-- ISI Article Identifier: 000250414600112.-- Printed version Sep 15, 2007.-- Issue title: ECOSS-24, Proceedings of the 24th European Conference on Surface Science (Paris, Sep 4-8, 2006).
Publisher version (URL)http://dx.doi.org/10.1016/j.susc.2007.04.081
URIhttp://hdl.handle.net/10261/13068
DOI10.1016/j.susc.2007.04.081
ISSN0039-6028
Appears in Collections:(CAB) Artículos
(ICMM) Artículos

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