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Título

Structural study of electrochemically-synthesized Ag2Cu2O4. A novel oxide sensitive to irradiation

AutorMuñoz Rojas, David CSIC ORCID; Fraxedas, J. CSIC ORCID ; Oró, Judith CSIC ORCID; Gómez-Romero, P. CSIC ORCID ; Casañ Pastor, Nieves CSIC ORCID
Palabras claveSilver copper oxides
Ag2Cu2O4
AgCuO2
Structural refinement
Electrochemical
Solid state
Fecha de publicación2002
EditorElsevier
CitaciónCrystal Engineering 5(3-4): 459-467 (2002)
ResumenThe structure of Ag2Cu2O4 synthesized by electrochemical oxidation of its precursor Ag2Cu2O3 is studied under a new perspective. Irradiation of the oxide with X-ray beam transforms the electronic structure of the phase by redistributing the internal charge within the material. The refined structure shows several possibilities all with metals in the same arrangement, but with oxygen atoms distributed in a rather disordered way. This is typical of ionic conductors.
URIhttp://hdl.handle.net/10261/129851
DOI10.1016/S1463-0184(02)00057-6
Identificadoresdoi: 10.1016/S1463-0184(02)00057-6
issn: 1463-0184
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