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Synthesis deintercalation and transport properties of a mixed-valence derivative of the layered oxide HLaNb2O7

AuthorsPalacín, M. Rosa ; Lira-Cantú, Mónica ; García, J. L.; Caldes, M. T.; Casañ Pastor, Nieves ; Fuertes, Amparo ; Gómez-Romero, P.
Issue Date1996
CitationMaterials Research Bulletin 31(2): 217-225 (1996)
AbstractWe have synthesized mixed-valence derivatives of the layered oxide HLa Nb2O7, structurally related to perovskite, by chemical reduction, either at room temperature or at 650°C. The thermal behavior of this compound, its structure and change in transport properties upon high temperature doping are discussed. High temperature reduction turns the white insulating precursor into a mixed-valence blue bronze with a layered structure and semiconducting-like properties.
Identifiersdoi: 10.1016/0025-5408(95)00179-4
issn: 0025-5408
Appears in Collections:(ICMAB) Artículos
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