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Nitrogen-containing ionic liquids: Biodegradation studies and utility in base-mediated reactions

AutorFord, Leigh; Ylijoki, Kai E O; García, María Teresa ; Singer, Robert D.; Scammells, Peter J.
Palabras claveDensity functional theory
Molecular calculations
Mediated reactions
Tertiary amine
Ionic liquids
Fecha de publicación2015
EditorCSIRO Publishing
CitaciónAustralian Journal of Chemistry
ResumenSeveral ionic liquids (ILs) were prepared in order to study the susceptibility of various cores and substituents to biodegradability using the 'CO2 headspace' test (ISO 14593). Several of the ILs contained tertiary amine substituents and were tested as solvents and reagents for several base mediated processes including Suzuki-Miyaura, Sonogashira, Knoevenagel, and Morita-Baylis-Hilman reactions. It was found that although these ILs contain basic functionality, they do not promote base mediated reactions. Density functional theory molecular calculations confirmed that the protonation of these ILs is energetically unfavourable
Versión del editorhttp://www.publish.csiro.au/paper/CH14499.htm
URIhttp://hdl.handle.net/10261/129436
DOI10.1071/CH14499
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