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http://hdl.handle.net/10261/129237
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Campo DC | Valor | Lengua/Idioma |
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dc.contributor.author | Dikhtiarenko, Alla | es_ES |
dc.contributor.author | Villanueva-Delgado, Pedro | es_ES |
dc.contributor.author | Valiente, Rafael | es_ES |
dc.contributor.author | García, José R. | es_ES |
dc.contributor.author | Gimeno, José | es_ES |
dc.date.accessioned | 2016-02-19T10:58:12Z | - |
dc.date.available | 2016-02-19T10:58:12Z | - |
dc.date.issued | 2016 | - |
dc.identifier.citation | Polymers 8(2): 48 (2016) | es_ES |
dc.identifier.issn | 2073-4360 | - |
dc.identifier.uri | http://hdl.handle.net/10261/129237 | - |
dc.description | This article belongs to the Special Issue Coordination Polymers: New Materials for Multiple Applications. | es_ES |
dc.description.abstract | A series of 3D oxalate-bridged ruthenium-based coordination polymers with the formula of {[ZII(bpy)3][MIRu(C2O4)3]}n (ZII = Zn2+ (1), Cu2+ (3, 4), Ru2+ (5, 6), Os2+ (7, 8); MI = Li+, Na+; bpy = 2,2’-bipyridine) and {[ZnII(bpy)3](H2O)[LiRu(C2O4)3]}n (2) has been synthesized at room temperature through a self-assembly reaction in aqueous media and characterized by single-crystal and powder X-ray diffraction, elemental analysis, infrared and diffuse reflectance UV–Vis spectroscopy and thermogravimetric analysis. The crystal structures of all compounds comprise chiral 3D honeycomb-like polymeric nets of the srs-type, which possess triangular anionic cages where [ZII(bpy)3]2+ cationic templates are selectively embedded. Structural analysis reveals that the electronic configuration of the cationic guests is affected by electrostatic interaction with the anionic framework. Moreover, the MLCT bands gaps values for 1–8 can be tuned in a rational way by judicious choice of [ZII(bpy)3]2+ guests. The 3D host-guest polymeric architectures can be used as self-supported heterogeneous photocatalysts for the reductive splitting of water, exhibiting photocatalytic activity for the evolution of H2 under UV light irradiation. | es_ES |
dc.description.sponsorship | The authors thank FEDER and Spanish MINECO for financial support under Projects MAT2013-40950-R, UCAN08-4E-008, MAT2012-38664-C02-1 and Consolider ORFEO. Alla Dikhtiarenko also thanks the Spanish Ministerio de Educación, Cultura y Deporte for their pre-doctoral FPU grant (AP2008-03942). | es_ES |
dc.description.sponsorship | We acknowledge support by the CSIC Open Access Publication Initiative through its Unit of Information Resources for Research (URICI). | es_ES |
dc.language.iso | eng | es_ES |
dc.publisher | Multidisciplinary Digital Publishing Institute | es_ES |
dc.relation | info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MAT2013-40950-R | - |
dc.relation.isversionof | Publisher's version | es_ES |
dc.rights | openAccess | - |
dc.subject | Water splitting | es_ES |
dc.subject | Hydrogen evolution | es_ES |
dc.subject | Coordination polymers | es_ES |
dc.subject | Photocatalysts | es_ES |
dc.title | Tris(bipyridine)metal(II)-templated assemblies of 3D alkali-ruthenium oxalate coordination frameworks: Crystal structures, characterization and photocatalytic activity in water reduction | es_ES |
dc.type | artículo | - |
dc.identifier.doi | 10.3390/polym8020048 | - |
dc.description.peerreviewed | Peer reviewed | es_ES |
dc.relation.publisherversion | http://dx.doi.org/10.3390/polym8020048 | es_ES |
dc.rights.license | http://creativecommons.org/licenses/by/4.0/ | es_ES |
dc.contributor.funder | Ministerio de Educación, Cultura y Deporte (España) | es_ES |
dc.contributor.funder | Ministerio de Economía y Competitividad (España) | es_ES |
dc.contributor.funder | Consejo Superior de Investigaciones Científicas (España) | es_ES |
dc.contributor.funder | European Commission | es_ES |
dc.relation.csic | Sí | es_ES |
dc.identifier.funder | http://dx.doi.org/10.13039/501100003176 | es_ES |
dc.identifier.funder | http://dx.doi.org/10.13039/501100003329 | es_ES |
dc.identifier.funder | http://dx.doi.org/10.13039/501100003339 | es_ES |
dc.identifier.funder | http://dx.doi.org/10.13039/501100000780 | es_ES |
dc.identifier.pmid | 30979145 | - |
dc.type.coar | http://purl.org/coar/resource_type/c_6501 | es_ES |
item.languageiso639-1 | en | - |
item.fulltext | With Fulltext | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.cerifentitytype | Publications | - |
item.grantfulltext | open | - |
item.openairetype | artículo | - |
Aparece en las colecciones: | (CINN) Artículos |
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Fichero | Descripción | Tamaño | Formato | |
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Water Reduction.pdf | 3,48 MB | Adobe PDF | Visualizar/Abrir |
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