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dc.contributor.authorDikhtiarenko, Allaes_ES
dc.contributor.authorVillanueva-Delgado, Pedroes_ES
dc.contributor.authorValiente, Rafaeles_ES
dc.contributor.authorGarcía, José R.es_ES
dc.contributor.authorGimeno, Josées_ES
dc.date.accessioned2016-02-19T10:58:12Z-
dc.date.available2016-02-19T10:58:12Z-
dc.date.issued2016-
dc.identifier.citationPolymers 8(2): 48 (2016)es_ES
dc.identifier.issn2073-4360-
dc.identifier.urihttp://hdl.handle.net/10261/129237-
dc.descriptionThis article belongs to the Special Issue Coordination Polymers: New Materials for Multiple Applications.es_ES
dc.description.abstractA series of 3D oxalate-bridged ruthenium-based coordination polymers with the formula of {[ZII(bpy)3][MIRu(C2O4)3]}n (ZII = Zn2+ (1), Cu2+ (3, 4), Ru2+ (5, 6), Os2+ (7, 8); MI = Li+, Na+; bpy = 2,2’-bipyridine) and {[ZnII(bpy)3](H2O)[LiRu(C2O4)3]}n (2) has been synthesized at room temperature through a self-assembly reaction in aqueous media and characterized by single-crystal and powder X-ray diffraction, elemental analysis, infrared and diffuse reflectance UV–Vis spectroscopy and thermogravimetric analysis. The crystal structures of all compounds comprise chiral 3D honeycomb-like polymeric nets of the srs-type, which possess triangular anionic cages where [ZII(bpy)3]2+ cationic templates are selectively embedded. Structural analysis reveals that the electronic configuration of the cationic guests is affected by electrostatic interaction with the anionic framework. Moreover, the MLCT bands gaps values for 1–8 can be tuned in a rational way by judicious choice of [ZII(bpy)3]2+ guests. The 3D host-guest polymeric architectures can be used as self-supported heterogeneous photocatalysts for the reductive splitting of water, exhibiting photocatalytic activity for the evolution of H2 under UV light irradiation.es_ES
dc.description.sponsorshipThe authors thank FEDER and Spanish MINECO for financial support under Projects MAT2013-40950-R, UCAN08-4E-008, MAT2012-38664-C02-1 and Consolider ORFEO. Alla Dikhtiarenko also thanks the Spanish Ministerio de Educación, Cultura y Deporte for their pre-doctoral FPU grant (AP2008-03942).es_ES
dc.description.sponsorshipWe acknowledge support by the CSIC Open Access Publication Initiative through its Unit of Information Resources for Research (URICI).es_ES
dc.language.isoenges_ES
dc.publisherMultidisciplinary Digital Publishing Institutees_ES
dc.relationMINECO/ICTI2013-2016/MAT2013-40950-R-
dc.relation.isversionofPublisher's versiones_ES
dc.rightsopenAccess-
dc.subjectWater splittinges_ES
dc.subjectHydrogen evolutiones_ES
dc.subjectCoordination polymerses_ES
dc.subjectPhotocatalystses_ES
dc.titleTris(bipyridine)metal(II)-templated assemblies of 3D alkali-ruthenium oxalate coordination frameworks: Crystal structures, characterization and photocatalytic activity in water reductiones_ES
dc.typeartículo-
dc.identifier.doi10.3390/polym8020048-
dc.description.peerreviewedPeer reviewedes_ES
dc.relation.publisherversionhttp://dx.doi.org/10.3390/polym8020048es_ES
dc.rights.licensehttp://creativecommons.org/licenses/by/4.0/es_ES
dc.contributor.funderMinisterio de Educación, Cultura y Deporte (España)es_ES
dc.contributor.funderMinisterio de Economía y Competitividad (España)es_ES
dc.contributor.funderConsejo Superior de Investigaciones Científicas (España)es_ES
dc.contributor.funderEuropean Commissiones_ES
dc.relation.csices_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100003176es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100003329es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100003339es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100000780es_ES
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