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dc.contributor.authorSha, Manas K.-
dc.contributor.authorMorón, M. Carmen-
dc.contributor.authorPalacio, Fernando-
dc.contributor.authorBernal-Villamil, Iván-
dc.date.accessioned2016-02-08T09:14:01Z-
dc.date.available2016-02-08T09:14:01Z-
dc.date.issued2005-
dc.identifierdoi: 10.1021/ic048947f-
dc.identifierissn: 0020-1669-
dc.identifiere-issn: 1520-510X-
dc.identifier.citationInorganic Chemistry 44(5): 1354-1361 (2005)-
dc.identifier.urihttp://hdl.handle.net/10261/128819-
dc.description.abstractA novel molecular based magnet of three-dimensional (3-D) cyanide-bridged bimetallic assembly, [{(323)Ni}3{FeIII(CN)6}2]n·2nH2O where 323 = N,N‘-bis(3-aminopropyl) ethylenediamine, was synthesized and structurally characterized. The compound crystallizes in the orthorhombic space group Pbca with a = 15.6560 Å, b = 15.2910 Å, c = 50.9120 Å, and Z = 8. The assembly has two intercalated 3-D networks created by FeIII−CN−NiII−NC−FeIII linkages. The ferricyanide anion adopts both facial and meridional arrangements through the linkage. Interesting magnetic properties including 3-dimensional magnetic ordering were revealed. The assembly displays 3-dimensional magnetic ordering below 5.2 ± 0.1 K and field-induced magnetic behavior below 5.1 ± 0.1 K and above 1.15 ±0.05 kOe.-
dc.description.sponsorshipWe thank the Robert A. Welch Foundation for support of these studies (Grant 592 to I.B.), and for postdoctoral support to M.K.S., M.C.M., and F.P., we acknowledge the Comision Interministerial de Ciencia y Tecnologia (Grant MAT2001-3507-C02-02) for the support.-
dc.publisherAmerican Chemical Society-
dc.rightsclosedAccess-
dc.titleA new bimetallic intercalated 3-D assembly magnet [{(323)Ni}3{FeIII(CN)6}2]n·12nH2O (323 = N,N'-bis(3-aminopropyl) ethylenediamine): An unprecedented concomitant presence of meridional and facial arrangment of ferricyanide anion-
dc.typeartículo-
dc.identifier.doi10.1021/ic048947f-
dc.date.updated2016-02-08T09:14:03Z-
dc.description.versionPeer Reviewed-
dc.language.rfc3066eng-
dc.contributor.funderComisión Interministerial de Ciencia y Tecnología, CICYT (España)-
dc.contributor.funderWelch Foundation-
dc.relation.csic-
dc.identifier.funderhttp://dx.doi.org/10.13039/501100007273es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/100000928es_ES
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