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Title

Crystal structure and magnetic measurements of [Cr(en)3] [ZnCl4]Cl

AuthorsPons, Josefina; Casabó, Jaume ; Palacio, Fernando; Morón, M. Carmen; Solans, X.; Carlin, Richard L.
Issue Date1988
PublisherElsevier
CitationInorganica Chimica Acta 146(2): 161-165 (1988)
AbstractThe compound [Cr(en)3][ZnCl4]Cl has been synthesized by reaction of CrCl3·6H2O, Zn and [Cr(en)3]2(SO4)3 in HCl. Its molecular and crystalline structure was determined by X-ray diffraction methods, being monoclinic, P21/c, a=21.215(3), b=12.532(2), c=13.707(2) Å, β=95.21°, V= 3629(2) Å3, Dx=1.738g cm−3, MW=474.9, Z= 8, F(000)=1928, λ(Mo Kα)=0.71069 Å, μ(Mo Kα)= 27.04 cm−1, 288 K. No significant exchange interactions between Cr(III) cations in the crystalline lattice were found. Curie-Weiss behavior was found in the three directions tested (g1=2.06±0.02,g2= 2.08±0.02,g3=2.09±0.01), T=1.2-1.4 K.
URIhttp://hdl.handle.net/10261/128656
DOI10.1016/S0020-1693(00)80603-9
Identifiersdoi: 10.1016/S0020-1693(00)80603-9
issn: 0020-1693
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