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Título

Adaptable Ultraviolet Refl ecting Polymeric Multilayer Coatings of High Refractive Index Contrast

AutorCastro Smirnov, José R. CSIC; Ito, M.; Calvo, Mauricio E. CSIC ORCID ; López-López, Carmen CSIC ORCID; Jiménez-Solano, Alberto CSIC ORCID; Galisteo-López, Juan F.; Zavala-Rivera, Paul; Tanaka, K.; Sivaniah, Easan; Míguez, Hernán CSIC ORCID
Fecha de publicación2015
EditorWiley-VCH
CitaciónAdvanced Optical Materials, 3:1633-1639 (2015)
ResumenA synthetic route is demonstrated to build purely polymeric nanostructured multilayer coatings, adaptable to arbitrary surfaces, and capable of effi ciently blocking by refl ection a targeted and tunable ultraviolet (UV) range. Refl ection properties are determined by optical interference between UV light beams refl ected at the interfaces between polystyrene layers of different porosity and hence refractive index. As no dopant absorber intervenes in the shielding effect, polymer degradation effects are prevented. Alternated porosity results from the modulation of photochemical effects at the few tens of nanometers length scale, combined with the collective osmotic shock induced during the processing of the precursor diblock copolymer fi lm. Experimental evidence of the application of this method to coat rough surfaces with smooth and conformal UV protecting fi lms is provided
Versión del editorhttp://dx.doi.org/10.1002/adom.201500209
URIhttp://hdl.handle.net/10261/128382
DOI10.1002/adom.201500209
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