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Title

Dynamic assembly of a zinc-templated bifunctional organocatalyst in the presence of water for the asymmetric aldol reaction

AuthorsSerra-Pont, Anna; Alfonso, Ignacio ; Jimeno, Ciril ; Solà Oller, Jordi
Keywordsabsorption spectroscopy
aldol reaction
asymmetric synthesis
nuclear magnetic resonance
nuclear magnetic resonance
stereochemistry
Issue Date2015
PublisherRoyal Society of Chemistry (UK)
CitationChemical Communications
AbstractA bifunctional organocatalytic system consisting of simple pyridine ligands containing separate catalytic functionalities was assembled using ZnCl2. This novel metal-templated catalyst furnished high yields and stereoselectivities towards the aldol reaction. The addition of controlled amounts of water turned out to be crucial to dissolve the system and achieve optimal results.
Publisher version (URL)DOI: 10.1039/c5cc07847d http://pubs.rsc.org/en/content/articlepdf/2015/cc/c5cc07847d
URIhttp://hdl.handle.net/10261/128325
DOIhttp://dx.doi.org/10.1039/c5cc07847d
Appears in Collections:(IQAC) Artículos
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