Please use this identifier to cite or link to this item: http://hdl.handle.net/10261/12808
Share/Export:
logo share SHARE logo core CORE BASE
Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL | DATACITE
Title

The biomimetic synthesis of trans-(1β-h,5α-h)-guaianolides

AuthorsGonzález, Antonio G.; Galindo, Antonio CSIC ORCID; Afonso, M. Mar; Mansilla, Horacio CSIC; Palenzuela, José A.; Gómez Rodríguez, Mª Ángeles; Martínez-Ripoll, Martín CSIC ORCID
Issue Date1988
PublisherElsevier
CitationTetrahedron 44(14): 4575-4584 (1988)
Abstract1-epigallicin 11 underwent biomimetic cyclization to trans-(1β-H,5α-H)-guaianolide 22,the stereoespecificity of this cyclization being credited to the fact that it took place via the reacting TC conformation 27. The epimeric nor-guaianolides 15 and 17 were prepared and their rearrangements studied. The biogenetic implications of these processes are discussed.
Description10 pages, 4 figures, 5 tables, 2 schemes.
Lists of observed and calculated structure factors, final anisotrooic parameters for heavy atoms, positional and thermal parameters for H-atoms, are available from the Cambridge Crystallographic Data Centre (CCDC), University Chemical Laboratory, Lensfield Road, Cambridge CB2.
Publisher version (URL)http://dx.doi.org/10.1016/S0040-4020(01)86160-3
URIhttp://hdl.handle.net/10261/12808
DOI10.1016/S0040-4020(01)86160-3
ISSN0040-4020
Appears in Collections:(IPNA) Artículos
(IQFR) Artículos

Show full item record
Review this work

SCOPUSTM   
Citations

12
checked on May 17, 2022

WEB OF SCIENCETM
Citations

12
checked on May 17, 2022

Page view(s)

435
checked on May 19, 2022

Google ScholarTM

Check

Altmetric

Dimensions


WARNING: Items in Digital.CSIC are protected by copyright, with all rights reserved, unless otherwise indicated.