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dc.contributor.authorVillar, V. deles_ES
dc.contributor.authorBarrio, B.es_ES
dc.contributor.authorHelmi, Arashes_ES
dc.contributor.authorVan Sint Annaland, M.es_ES
dc.contributor.authorGallucci, Faustoes_ES
dc.contributor.authorGarcía Fierro, José Luises_ES
dc.contributor.authorNavarro Yerga, Rufino Manueles_ES
dc.date.accessioned2015-12-30T13:05:42Z-
dc.date.available2015-12-30T13:05:42Z-
dc.date.issued2015-12-
dc.identifier.citationCatalysis Todayes_ES
dc.identifier.issn0920-5861-
dc.identifier.urihttp://hdl.handle.net/10261/127251-
dc.descriptionIn Press-
dc.description.abstractThe catalytic performance of RePt/CeO2-TiO2 catalysts for the WGS reaction under conditions compatible with membrane reactor was investigated. The WGS activity and stability of the Pt/CeO2-TiO2 catalyst was significantly influenced by the addition of rhenium. The intrinsic WGS activity per atom of platinum improves with the addition of Re to Pt/ CeO2-TiO2 catalyst. The addition of rhenium also has a beneficial effect on its stability under WGS conditions compatible with membrane reactor use. The improvement in WGS activity and stability is proposed to be associated with the improvement in the reduction behaviour of the highly dispersed CeO2 and ReOx species present in the bimetallic RePt catalyst respect to the monometallic Pt/CeTi counterpart and to the presence of rhenium species in close contact with Pt that could introduce an additional redox activity sites stable under WGS conditions and/or prevent the sintering of Pt crystallites under WGS conditionses_ES
dc.description.sponsorshipThe research under this project is receiving funding from the European Union Seventh Framework Programme (FP7/2007-2013) under grant agreement NMP3-LA.2011-262840 (DEMCAMER) and by CAM under grant S2013/MAE-2882.-
dc.language.isoenges_ES
dc.publisherElsevieres_ES
dc.relationS2013/MAE-2882/RESTOENEes_ES
dc.relationS2013/MAE-2882es_ES
dc.relationinfo:eu-repo/grantAgreement/EC/FP7/262840es_ES
dc.relation.isversionofPostprintes_ES
dc.rightsopenAccessen_EN
dc.subjectplatinumes_ES
dc.subjectrheniumes_ES
dc.subjectceriaes_ES
dc.subjecttitaniaes_ES
dc.subjectWGSes_ES
dc.subjectfluidizationes_ES
dc.subjectmembrane reactores_ES
dc.titleEffect of Re addition on the WGS activity and stability of Pt/CeO2-TiO2 catalyst form membrane reactor applicationses_ES
dc.typeArtículoes_ES
dc.identifier.doi10.1016/j.cattod.2015.11.013-
dc.description.peerreviewedPeer reviewedes_ES
dc.relation.publisherversionhttp://dx.doi.org/10.1016/j.cattod.2015.11.013es_ES
dc.contributor.funderComunidad de Madrides_ES
dc.contributor.funderEuropean Commissiones_ES
dc.relation.csices_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100000780es_ES
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