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Título: | Influence of Ni evironment on the reactivity of Ni-Mg-Al catalyst for the acetone steam reforming reaction |
Autor: | Guil López, Ruth CSIC ORCID; Navarro Yerga, Rufino Manuel CSIC ORCID ; Ismail, A. A.; Al-Sayari, S. A.; García Fierro, José Luis CSIC ORCID | Palabras clave: | Nickel Catalysts hydrotalcite hydrogen production Bio-oils acetone steam reforming |
Fecha de publicación: | 24-abr-2015 | Editor: | Elsevier | Citación: | International Journal of Hydrogen Energy 40(15): 5289-5296 (2015) | Resumen: | Steam reforming of acetone, as representative molecule of bio-oil, was investigated over different Ni-Mg-Al oxides with different Ni-environments which were obtained by the preparation of different Ni-Mg-Al materials: Ni-supported, Ni-mixed oxides and Ni like-spinel structures. Physico-chemical characterization of samples showed different Ni-support interactions depending on the nature of the support and the method of preparation. Ni-incorporation into the Mg-Al structure increases its stability. Reforming activity results showed that the Ni-environment interaction plays an essential role on the catalytic behaviour of Ni-Mg-Al catalysts. The sequence of gasification capacity over Ni-Mg-Al samples points out that acidity of supports participates in the acetone reforming mechanism over these catalysts | Versión del editor: | htttp://dx.doi.org/10.1016/j.ijhydene.2015.01.59 | URI: | http://hdl.handle.net/10261/127250 | DOI: | 10.1016/j.ijhydene.2015.01.159 | ISSN: | 0360-3199 |
Aparece en las colecciones: | (ICP) Artículos |
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