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Selective CO2 capture in metal-organic frameworks with azine-functionalized pores generated by mechanosynthesis

AutorMasoomi, Mohammad Y.; Stylianou, Kyriakos C.; Morsali, Ali; Retailleau, Pascal; Maspoch, Daniel
Fecha de publicación2014
EditorAmerican Chemical Society
CitaciónCrystal Growth and Design 14(5): 2092-2096 (2014)
ResumenTwo new three-dimensional porous Zn(II)-based metal-organic frameworks, containing azine-functionalized pores, have been readily and quickly isolated via mechanosynthesis, by using a nonlinear dicarboxylate and linear N-donor ligands. The use of nonfunctionalized and methyl-functionalized N-donor ligands has led to the formation of frameworks with different topologies and metal-ligand connectivities and therefore different pore sizes and accessible volumes. Despite this, both metal-organic frameworks (MOFs) possess comparable BET surface areas and CO2 uptakes at 273 and 298 K at 1 bar. The network with narrow and interconnected pores in three dimensions shows greater affinity for CO2 compared to the network with one-dimensional and relatively large pores-attributable to the more effective interactions with the azine groups. © 2014 American Chemical Society.
URIhttp://hdl.handle.net/10261/127173
DOI10.1021/cg500033b
Identificadoresdoi: 10.1021/cg500033b
issn: 1528-7483
e-issn: 1528-7505
Aparece en las colecciones: (CIN2) Artículos
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