English   español  
Please use this identifier to cite or link to this item: http://hdl.handle.net/10261/126939
Share/Impact:
Statistics
logo share SHARE logo core CORE   Add this article to your Mendeley library MendeleyBASE

Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL
Exportar a otros formatos:
DC FieldValueLanguage
dc.contributor.authorSantiuste, J. M.-
dc.contributor.authorQuintanilla-López, Jesús Eduardo-
dc.contributor.authorBecerra, R.-
dc.contributor.authorGutiérrez, C.-
dc.contributor.authorLebrón-Aguilar, R.-
dc.date.accessioned2015-12-15T14:33:14Z-
dc.date.available2015-12-15T14:33:14Z-
dc.date.issued2015-
dc.identifierdoi: 10.1007/s10337-015-2924-9-
dc.identifierissn: 0009-5893-
dc.identifiere-issn: 1612-1112-
dc.identifier.citationChromatographia 78: 1071-1081 (2015)-
dc.identifier.urihttp://hdl.handle.net/10261/126939-
dc.description.abstractIsothermal retention indices (I) at 333–413 K on 12 stationary phases (SPs) covering a wide polarity range of a variety of volatile solutes belonging to 7 one-heteroatom chemical function series and 10 non-series solutes have been determined. The I values were computed with a method (LQG method) which does not require the determination of holdup times of the chromatographic column. I values of some compounds never before studied are reported. The influence on the retention indices of the column temperature, methylene number, and polarity of both the stationary phase and the solute has been studied. The solvation parameter model (SPM) as a function of I has been used for predicting I values, and for unraveling the influence of the polarity of stationary phase and solute on the retention indices. Seeley et al.’s formulation of the SPM has been used for quantifying the influence of polar and non-polar interactions on the I, and for checking the agreement between calculated and experimental values. According to our results, the I values obtained by the modified SPM can be considered equal to the experimental I values at the 99 % confidence level.-
dc.description.sponsorshipAuthors thank financial support from the Comunidad of Madrid and European funding from FEDER program (project S2013/ABI-3028, AVANSECAL).-
dc.publisherSpringer-
dc.rightsclosedAccess-
dc.subjectSolvation parameter model-
dc.subjectIsothermal retention indices-
dc.subjectColumn temperature-
dc.subjectSolute–stationary phase interactions-
dc.subjectGas chromatography-
dc.titleFactors Influencing the Isothermal Retention Indices of 51 Solutes on 12 Stationary Phases of Different Polarity: Applicability of the Solvation Parameter Model-
dc.typeartículo-
dc.identifier.doi10.1007/s10337-015-2924-9-
dc.date.updated2015-12-15T14:33:14Z-
dc.description.versionPeer Reviewed-
dc.language.rfc3066eng-
dc.contributor.funderEuropean Science Foundation-
dc.contributor.funderComunidad de Madrid-
dc.relation.csic-
dc.identifier.funderhttp://dx.doi.org/10.13039/501100000782es_ES
Appears in Collections:(IQOG) Artículos
(IQFR) Artículos
Files in This Item:
File Description SizeFormat 
accesoRestringido.pdf15,38 kBAdobe PDFThumbnail
View/Open
Show simple item record
 

Related articles:


WARNING: Items in Digital.CSIC are protected by copyright, with all rights reserved, unless otherwise indicated.