Por favor, use este identificador para citar o enlazar a este item:
http://hdl.handle.net/10261/126902
COMPARTIR / EXPORTAR:
SHARE CORE BASE | |
Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL | DATACITE | |
Título: | Four molecular superconductors isolated as nanoparticles |
Autor: | Caro, Dominique de; Faulmann, Christophe; Valade, Lydie; Fraxedas, J. CSIC ORCID ; Ballesteros, Belén CSIC ORCID | Palabras clave: | Nanoparticles Superconductors Bechgaard salts Ionic liquids Electrochemistry |
Fecha de publicación: | 2014 | Editor: | Wiley-VCH | Citación: | European Journal of Inorganic Chemistry 2014(24): 4010-4016 (2014) | Resumen: | (TMTSF)2PF6 and (TMTSF)2ClO4 Bechgaard salts, (BEDT-TTF)2I3, and TTF[Ni(dmit)2]2 [TMTSF = tetramethyltetraselenafulvalene; BEDT-TTF = bis(ethylenedithio)tetrathiafulvalene; TTF = tetrathiafulvalene; dmit = 1,3-dithiole-2-thione-4,5-dithiolate] are among the most popular molecular superconductors. They are grown as nanoparticles that exhibit properties in agreement with those of the bulk. The shape, size, and homogeneity of particles depend on the stabilizing agent and synthesis conditions. We report on the more recent conditions investigated (i) to produce nanoparticles of 35 nm for β-(BEDT-TTF)2I3, (ii) to reduce the particle size to 10–15 nm for TTF[Ni(dmit)2]2 and 3–5 nm for (TMTSF)2ClO4, and (iii) to improve the growth duration from days to one hour for (TMTSF)2PF6. Finally, we report evidence of superconductivity in (TMTSF)2ClO4 particles. | URI: | http://hdl.handle.net/10261/126902 | DOI: | 10.1002/ejic.201402007 | Identificadores: | doi: 10.1002/ejic.201402007 issn: 1434-1948 e-issn: 1099-0682 |
Aparece en las colecciones: | (CIN2) Artículos |
Ficheros en este ítem:
Fichero | Descripción | Tamaño | Formato | |
---|---|---|---|---|
accesoRestringido.pdf | 15,38 kB | Adobe PDF | Visualizar/Abrir |
CORE Recommender
SCOPUSTM
Citations
16
checked on 18-abr-2024
WEB OF SCIENCETM
Citations
15
checked on 27-feb-2024
Page view(s)
163
checked on 19-abr-2024
Download(s)
30
checked on 19-abr-2024
Google ScholarTM
Check
Altmetric
Altmetric
NOTA: Los ítems de Digital.CSIC están protegidos por copyright, con todos los derechos reservados, a menos que se indique lo contrario.