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Conductometric determination of ammonium by a multisyringe flow injection system applying gas diffusion

AutorHenríquez, Camelia; Horstkotte, Burkhard ; Cerdà, Víctor
Palabras claveammonium
conductometric detection
gas diffusion
multisyringe flow injection analysis
natural waters
Fecha de publicación19-dic-2012
EditorTaylor & Francis
CitaciónInternational Journal of Environmental Analytical Chemistry 93(12): 1236-1252 (2013)
ResumenA multisyringe flow injection system (MSFIA) coupled to a gas-diffusion cell has been developed for the conductometric determination of ammonium in different water samples. Operation strategies, membrane, reagent concentrations, and flow rates have been studied to optimize the sensitivity of detection and to fit the required working range. The proposed MSFIA system has been compared with former FIA and SIA systems using gas diffusion. The system was applied to the determination of ammonium in water samples of different matrices in order to evaluate its performance. These samples were coastal waters, pond waters, and compost aqueous extracts. Good recoveries of 102 ± 13% were obtained and no significant differences with the reference methods were found. The system can be used for a wide concentration range of ammonia, from 0.075 to 360 mg L-1, without sample dilution and with a precision better than 2% of RSD. The throughput of the method was 32 injections per hour. © 2013 Copyright Taylor and Francis Group, LLC.
Versión del editorhttp://dx.doi.org/10.1080/03067319.2012.746322
Identificadoresdoi: 10.1080/03067319.2012.746322
issn: 0306-7319
Aparece en las colecciones: (IMEDEA) Artículos
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