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Title

1-(1,5-Dimethylhexyl)-3a,5b,12a,14a-tetramethyl-2,3,3a,4,5,5a,5b,11,12,13,14,14a-dodecahydro-1H,12aH-cyclopenta[1,2]phenanthro[7,8-b]indole

AuthorsLópez Rodríguez, Matías; Mazoir, Noureddine; Daoubi, Mourad; Reina, Matías ; Benharref, Ahmed
Issue DateDec-2007
PublisherWiley-Blackwell
CitationActa Crystallographica E 63: o4911 (2007)
AbstractThe title compound, C35H51N, is a semi-synthesized derivative obtained from 4α,14α-dimethyl-5α-cholest-8-en-3β-ol, a major triterpene isolated from Euphorbia officinarum latex. The molecular structure was established by H-1 and C-13 NMR spectroscopy and confirmed as having the stereochemistry at the new C11b stereocenter by single-crystal X-ray diffraction. The planar indole group is folded over the extended tetracyclic perhydrocyclopentanephenanthrene triterpene skeleton. There are no π-π interactions between the indole ring systems.
DescriptionAttached full-text file contains supporting information (12 pages).
Publisher version (URL)http://dx.doi.org/10.1107/S1600536807053913
URIhttp://hdl.handle.net/10261/12611
DOI10.1107/S1600536807053913
ISSN1600-5368
Appears in Collections:(IPNA) Artículos
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