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dc.contributor.authorGracia, Ismaeles_ES
dc.contributor.authorFeringán, Beatrizes_ES
dc.contributor.authorSerrano, José Luises_ES
dc.contributor.authorTermine, Robertoes_ES
dc.contributor.authorGolemme, Attilioes_ES
dc.contributor.authorOmenat, Anaes_ES
dc.contributor.authorBarberá, Joaquínes_ES
dc.date.accessioned2015-08-21T06:58:53Z-
dc.date.available2015-08-21T06:58:53Z-
dc.date.issued2015-01-
dc.identifier.citationChemistry - A European Journal 21(3): 1359-1369 (2015)es_ES
dc.identifier.issn0947-6539-
dc.identifier.urihttp://hdl.handle.net/10261/121299-
dc.description.abstractThe synthesis and characterisation of a family of block codendrimers consisting of highly versatile mesogenic and carbazole-containing 2,2-bis(hydroxymethyl)propionic acid (bis-MPA) dendrons are reported. The liquid-crystal behaviour was investigated by means of differential scanning calorimetry, polarised-light optical microscopy and X-ray diffraction. Depending on the chemical structure of the constituent dendrons, the codendrimers show lamellar or columnar mesophases. On the basis of the experimental results, models both at the molecular level and in the mesophase are proposed. The physical properties of the block codendrimers derived from the presence of the carbazole moiety in their structure were investigated: photoluminescence in solution and in the mesophase, electrochemical behaviour and hole transport. Electrodeposition of carbazole dendrons afforded a globular supramolecular conformation in which the mesogenic molecular side plays a key role.es_ES
dc.description.sponsorshipFinancial support from the MINECO-FEDER project CTQ2012–35692, and Diputación General de Aragón-Fondo Social Europeo (DGA-FSE) (Project E04) is gratefully acknowledged. I.G. acknowledges a MICINN-FPI fellowship. A.G. and R.T. acknowledge support from the European Community’s Seventh Framework Program (FP7 2007-2013) through the MATERIA Project (PONa3_00370) and from MIUR through the PRIN 2012JHFYMC project.es_ES
dc.language.isoenges_ES
dc.publisherWiley-VCHes_ES
dc.rightsclosedAccesses_ES
dc.subjectCharge transportes_ES
dc.subjectDendrimerses_ES
dc.subjectElectrodepositiones_ES
dc.subjectLiquid crystalses_ES
dc.subjectMesophaseses_ES
dc.titleFunctional carbazole liquid-crystal block codendrimers with optical and electronic propertieses_ES
dc.typeartículoes_ES
dc.identifier.doi10.1002/chem.201404555-
dc.description.peerreviewedPeer reviewedes_ES
dc.relation.publisherversionhttp://dx.doi.org/10.1002/chem.201404555es_ES
dc.identifier.e-issn1521-3765-
dc.contributor.funderMinisterio de Economía y Competitividad (España)es_ES
dc.contributor.funderEuropean Commissiones_ES
dc.contributor.funderDiputación General de Aragónes_ES
dc.contributor.funderMinisterio de Ciencia e Innovación (España)es_ES
dc.contributor.funderMinistero dell'Istruzione, dell'Università e della Ricercaes_ES
dc.relation.csices_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100003329es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100000780es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100004837es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100003407es_ES
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