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Título:	Manganese phthalocyanine derivatives synthesized by on-surface cyclotetramerization
Autor:	Piantek, Marten CSIC; Serrate, David CSIC ORCID ; Algarabel, Pedro A. CSIC ORCID; Ibarra, M. Ricardo CSIC ORCID
Fecha de publicación:	2014
Editor:	American Chemical Society
Citación:	Journal of Physical Chemistry C 118(31): 17895-17899 (2014)
Resumen:	We report a two-step on-surface synthesis of Mn phthalocyanine molecules from four tetracyanobenzene (TCNB) monomers through coordinative bonding with manganese adatoms. In the first step, the coevaporation of TCNB and Mn atoms leads to a metal-organic network stabilized by a combination of coordination and hydrogen (H) bonds. In the second step, annealing the coordination networks above room temperature results in individual Mn phthalocyanine molecules. The results shown here demonstrate the viability of an on-surface chemical synthesis strategy involving the reduction of the organic reagents by metal ions to produce metal-organic molecules. © 2014 American Chemical Society.
Descripción:	et al.
URI:	http://hdl.handle.net/10261/118344
DOI:	10.1021/jp506652j
Identificadores:	doi: 10.1021/jp506652j issn: 1932-7447 e-issn: 1932-7455
Aparece en las colecciones:	(ICMA) Artículos

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Manganese phthalocyanine derivatives synthesized by on-surface cyclotetramerization