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Title

A multifunctional magnetic material under pressure

AuthorsRodríguez-Velamazán, J. A.; Fabelo, Óscar; Beavers, Christine M.; Natividad, Eva; Evangelisti, Marco; Roubeau, Olivier
KeywordsNeutron diffraction
Pressure effects
Spin crossover
X-ray diffraction
Magnetic properties
Issue Date2014
PublisherWiley-VCH
CitationChemistry - A European Journal 20(26): 7956-7961 (2014)
AbstractFeII(Metz)6](FeIIIBr4) 2 (Metz=1-methyltetrazole) is one of the rare systems combining spin-crossover and long-range magnetic ordering. A joint neutron and X-ray diffraction and magnetometry study allows determining its collinear antiferromagnetic structure, and shows an increase of the Néel temperature from 2.4 K at ambient pressure, to 3.9 K at 0.95 GPa. Applied pressure also enables a full high-spin to low-spin switch at ambient temperature.
Publisher version (URL)http://dx.doi.org/10.1002/chem.201402046
URIhttp://hdl.handle.net/10261/118027
DOI10.1002/chem.201402046
Identifiersdoi: 10.1002/chem.201402046
issn: 0947-6539
e-issn: 1521-3765
Appears in Collections:(ICMA) Artículos
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