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A stable, mononuclear, cationic Pt(III) complex stabilised by bulky N-heterocyclic carbenes

AuthorsRivada-Wheelaghan, Orestes ; Ortuño, Manuel A.; García-Garrido, Sergio E.; Díez, Josefina; Alonso, Pablo J.; Lledós, Agustí; Conejero, Salvador
Issue Date2014
PublisherRoyal Society of Chemistry (UK)
CitationChemical Communications 50(11): 1299-1301 (2014)
AbstractThe thermally stable, paramagnetic Pt(III) complex [PtI2(IPr) 2][BArF] has been prepared by oxidation of the Pt(ii) complex [PtI2(IPr)2] with iodine in the presence of NaBArF. X-ray crystallographic studies revealed the mononuclear nature of this species with a square-planar geometry. EPR and DFT studies pointed out to a metal-centred radical. © The Royal Society of Chemistry.
Identifiersdoi: 10.1039/C3CC48553F
issn: 1359-7345
e-issn: 1364-548X
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