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dc.contributor.author | Visinescu, Diana | - |
dc.contributor.author | Fabelo, Oscar | - |
dc.contributor.author | Ruiz-Pérez, Catalina | - |
dc.contributor.author | Lloret, Francesc | - |
dc.contributor.author | Julve, Miguel | - |
dc.date.accessioned | 2015-07-13T11:02:52Z | - |
dc.date.available | 2015-07-13T11:02:52Z | - |
dc.date.issued | 2013 | - |
dc.identifier | doi: 10.1016/j.inoche.2013.06.037 | - |
dc.identifier | issn: 1387-7003 | - |
dc.identifier.citation | Inorganic Chemistry Communication 35: 252-254 (2013) | - |
dc.identifier.uri | http://hdl.handle.net/10261/117885 | - |
dc.description.abstract | A unique cyanide-bridge mixed-valence CuI/CuII clathrate of formula [CuI2(CN)3][{CuII(tren)}2(μ-CN)](CF3SO3)2 [tren = tris(2-aminoethyl)amine] containing cyanide-bridged [{CuII(tren)}2(μ-CN)]3 + binuclear cations stacked between anionic honeycomb layered copper(I) cyanide networks, was synthesized and structurally characterized by single crystal X-ray diffraction. Variable-temperature magnetic susceptibility studies showed that the cyanide bridge mediates a strong antiferromagnetic interaction between the copper(II) centers (J = − 160 cm− 1, the spin Hamiltonian being defined as H = − JSA⋅SB). | - |
dc.description.sponsorship | We gratefully acknowledge the financial support from the Romanian National Authority for Scientific Research and from the Spanish MICINN through the projects CNCS-UEFISCDI, PN-II-RU-TE-2011-3-0126, MAT2010-16981, MAT2011-27233-C02-02 and CTQ2007-61690. | - |
dc.publisher | Elsevier | - |
dc.rights | closedAccess | - |
dc.subject | Crystal structures | - |
dc.subject | Binuclear complex | - |
dc.subject | Cyanide bridge | - |
dc.subject | Magnetic properties | - |
dc.subject | Mixed-valence copper(I,II) complexes | - |
dc.title | Synthesis, crystal structure and magnetic properties of a new cyanide-bridged mixed-valence copper(I)/copper(II) clathrate | - |
dc.type | artículo | - |
dc.identifier.doi | 10.1016/j.inoche.2013.06.037 | - |
dc.date.updated | 2015-07-13T11:02:52Z | - |
dc.description.version | Peer Reviewed | - |
dc.language.rfc3066 | eng | - |
dc.contributor.funder | Ministerio de Ciencia e Innovación (España) | - |
dc.contributor.funder | National Authority for Scientific Research (Romania) | - |
dc.relation.csic | Sí | - |
dc.identifier.funder | http://dx.doi.org/10.13039/501100004837 | es_ES |
dc.type.coar | http://purl.org/coar/resource_type/c_6501 | es_ES |
item.fulltext | No Fulltext | - |
item.grantfulltext | none | - |
item.cerifentitytype | Publications | - |
item.openairetype | artículo | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
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