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Título: | Evolution of Mn and Co oxidation state on TbMn1-xCoxO3 compounds |
Autor: | Cuartero, Vera CSIC ORCID; Blasco, Javier CSIC ORCID; García, Joaquín CSIC ORCID; Lafuerza, Sara CSIC ORCID ; Subías, G. CSIC ORCID | Fecha de publicación: | 2013 | Editor: | Institute of Physics Publishing | Citación: | Journal of Physics: Conference Series 430(1): 012102 (2013) | Resumen: | Structural and electronic properties of TbMn1-xCoxO3 samples have been characterized by means of x-ray and neutron diffraction and x-ray absorption spectroscopic techniques. Crystallographic structure was refined from diffraction data, and samples show the orthorhombic distorted perovskite structure (Pbnm), being isostructural to TbMnO3, except for x=0.4, 0.5 and 0.6, where an ordered double perovskite structure (P21/n) is found. The electronic configuration of Mn and Co ions was obtained along the series from the chemical shift of the edge on x-ray absorption spectra, at the Mn and Co K-edges. Our results agree with a charge redistribution between Mn and Co ions, yielding a mixed valence state Mn3+/Mn4+ and Co3+/Co2+ for the whole series. | Descripción: | Trabajo presentado a la 15th International Conference on X-ray Absorption Fine Structure (XAFS15) celebrada del 22 al 28 de julio de 2012 en Pekín (China).-- Under the terms of the Creative Commons Attribution (CC BY) licence (creativecommons.org/licenses/by/3.0). | Versión del editor: | http://dx.doi.org/10.1088/1742-6596/430/1/012102 | URI: | http://hdl.handle.net/10261/117578 | DOI: | 10.1088/1742-6596/430/1/012102 | Identificadores: | doi: 10.1088/1742-6596/430/1/012102 issn: 1742-6588 e-issn: 1742-6596 |
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