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Title

Carbon nanotube mediated reduction in optical activity in polyaniline composite materials

AuthorsIn het Panhuis, Marc; Doherty, Kathie J.; Sainz, Raquel CSIC ORCID; Benito, Ana M. CSIC ORCID ; Maser, Wolfgang K. CSIC ORCID
KeywordsNanotubos de carbono
Nanocomposites
Polianilina
Actividad óptica
Issue Date16-Jan-2008
CitationJournal of Physical Chemistry C 112(5): 1441-1445 (2008)
AbstractOptically active composite materials were prepared by in situ polymerization of aniline in the presence of multiwalled carbon nanotubes, followed by doping with (R)-(-)-10-camphorsulfonic acid. The reduction in circular dichroism intensity with increasing nanotube loading fraction is attributed to changes in the ratio of “free” polymer versus polymer interacting with carbon nanotubes. These changes are shown to correspond to a decreasing polyaniline stereoselectivity with increasing nanotube loading fraction
Publisher version (URL)http://dx.doi.org/10.1021/jp077117v
URIhttp://hdl.handle.net/10261/11751
DOIhttp://dx.doi.org/10.1021/jp077117v
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