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http://hdl.handle.net/10261/117465
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Campo DC | Valor | Lengua/Idioma |
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dc.contributor.author | Salinas-Uber, Jorge | - |
dc.contributor.author | Barrios, L. A. | - |
dc.contributor.author | Roubeau, Olivier | - |
dc.contributor.author | Aromí, Guillem | - |
dc.date.accessioned | 2015-07-02T08:07:15Z | - |
dc.date.available | 2015-07-02T08:07:15Z | - |
dc.date.issued | 2013 | - |
dc.identifier.citation | Polyhedron 54: 8-12 (2013) | es_ES |
dc.identifier.issn | 0277-5387 | - |
dc.identifier.uri | http://hdl.handle.net/10261/117465 | - |
dc.description.abstract | The novel ligand 1,3-bis-(3-oxo-3-(2-hydroxyphenyl)-propionyl)-2-pyridine, H4L, is used here for the first time. In a reaction with Co(II) it produces the complex salt [Co8O(OH)(H2L) 6]NO3 (1), containing an octametallic cluster cation. The topology of this cluster, which encapsulates a rare (μ3-O) ⋯H⋯(μ3-O) at its interior, exhibits a remarkable similarity to the cofactor of nitrogenase FeMoco. It features intramolecular antiferromagnetic interactions, which can be simulated using a spin-only model, yielding an S = 0 spin ground state, lying very close to numerous excited states. | es_ES |
dc.description.sponsorship | GA thanks the Generalitat de Catalunya for the prize ICREA Academia 2008 and the ERC for a Starting Grant (258060 FuncMolQIP). The authors thank the Spanish MCI through CTQ2009-06959 (LAB) and MAT2011-24284 (OR), and the ERC for a Predoctoral Fellowship under Grant 258060 FuncMolQIP. | es_ES |
dc.language.iso | eng | es_ES |
dc.publisher | Elsevier | es_ES |
dc.rights | closedAccess | es_ES |
dc.title | A novel bis-β-diketonate ligand stabilizes a [Co(II)8] cage that encapsulates a (μ3-O)⋯H⋯(μ3-O) moiety | es_ES |
dc.type | artículo | es_ES |
dc.identifier.doi | 10.1016/j.poly.2013.02.014 | - |
dc.description.peerreviewed | Peer reviewed | es_ES |
dc.relation.publisherversion | http://dx.doi.org/10.1016/j.poly.2013.02.014 | es_ES |
dc.contributor.funder | Generalitat de Catalunya | - |
dc.contributor.funder | European Research Council | - |
dc.contributor.funder | Ministerio de Ciencia e Innovación (España) | - |
dc.relation.csic | Sí | es_ES |
dc.identifier.funder | http://dx.doi.org/10.13039/501100002809 | es_ES |
dc.identifier.funder | http://dx.doi.org/10.13039/501100000781 | es_ES |
dc.identifier.funder | http://dx.doi.org/10.13039/501100004837 | es_ES |
dc.type.coar | http://purl.org/coar/resource_type/c_6501 | es_ES |
item.openairetype | artículo | - |
item.cerifentitytype | Publications | - |
item.languageiso639-1 | en | - |
item.grantfulltext | none | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.fulltext | No Fulltext | - |
Aparece en las colecciones: | (ICMA) Artículos |
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accesoRestringido.pdf | 15,38 kB | Adobe PDF | Visualizar/Abrir |
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