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A new type of paddle-wheel coordination complex

AuthorsBarrios, L. A.; Borilovic, Ivana; Salinas-Uber, Jorge; Aguilà, D.; Roubeau, Olivier; Aromí, Guillem
Issue Date2013
PublisherRoyal Society of Chemistry (Great Britain)
CitationDalton Transactions 42(34): 12185-12192 (2013)
AbstractIn the presence of Na+ ions, the reaction of the ligand 2-hydroxy-1,3-bis-(3-oxo-3-(2-hydroxyphenyl)-propionyl)-benzene, H5L4, with M(AcO)2 salts (M = Mn, Co) gathers the conditions for the assembly of coordination complexes (NBu4)3[M2Na2(H2L4)3] (M = Mn(II) 1 and Co(II) 2), which exhibit a new paddle-wheel structure. The features of this new category of compounds are discussed as well as their magnetic properties and solution behaviour.
Identifiersdoi: 10.1039/c3dt51232K
issn: 1477-9226
e-issn: 1477-9234
Appears in Collections:(ICMA) Artículos
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