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Título: | p-Donors microstructuring on surface of polymer film by their noncovalent interactions with iodine |
Autor: | Traven, Valerii F.; Ivanov, Ivan V.; Dolotov, Sergei M.; Veciana, Jaume CSIC ORCID CVN; Lebedev, Victor CSIC; Shulga, Yurii М.; Khasanov, Salavat S.; Medvedev, Michael G.; Laukhina, Elena CSIC ORCID | Palabras clave: | Surfaces Chemical vapor deposition IR SEM Fluorescence Electrical Conductivity |
Fecha de publicación: | 15-jun-2015 | Editor: | Elsevier | Citación: | Materials Chemistry and Physics 160: 161-167 (2015) | Resumen: | Noncovalent (charge transfer) interaction between perylene and iodine in polycarbonate film provides formation of microstructured perylene layer on the polymer surface upon exposure of polymer film which contains dissolved perylene to solvent þ iodine vapors. The prepared bilayer film possesses a sensing effect to iodine vapors which can be observed by both fluorescence and electrical conductivity changes. Similar bilayer films have been prepared also with anthracene and phenothiazine as p-donors with use of different polymer matrixes. Interaction of iodine with polycyclic aromatic hydrocarbons (PAH) has also been studied by the M06-2x DFT calculations for better understanding of phenomenon of p-donors microstructuring on surface of polymer film. | Versión del editor: | http://dx.doi.org/10.1016/j.matchemphys.2015.04.020 | URI: | http://hdl.handle.net/10261/116699 | DOI: | 10.1016/j.matchemphys.2015.04.020 | ISSN: | 0254-0584 | E-ISSN: | 1879-3312 |
Aparece en las colecciones: | (ICMAB) Artículos |
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TRAVEN-MaterChemPhys-2015-postprint.pdf | 642,29 kB | Adobe PDF | Visualizar/Abrir |
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