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Título: | Mechanical and shape-memory properties of poly(mannitol sebacate)/cellulose nanocrystal nanocomposites |
Autor: | Sonseca, Águeda CSIC ORCID; Camarero-Espinosa, Sandra; Peponi, Laura CSIC ORCID; Weder, Christoph; Foster, J. E.; Kenny, José María CSIC ORCID; Giménez, Enrique | Palabras clave: | Cellulose nanocrystals Mechanical properties Nanocomposites Nanoparticles poly(polyol sebacate) Shape memory |
Fecha de publicación: | 2014 | Editor: | John Wiley & Sons | Citación: | Journal of Polymer Science, Part A: Polymer Chemistry 52: 3123-3133 (2014) | Resumen: | Polyesters based on polyols and sebacic acid, known as poly(polyol sebacate)s (PPS), are attracting considerable attention, as their properties are potentially useful in the context of soft-tissue engineering applications. To overcome the drawback that PPSs generally display rather low strength and stiffness, we have pursued the preparation of nanocomposites based poly(mannitol sebacate) (PMS), a prominent example of this materials family, with cellulose nanocrystals (CNCs). Nanocomposites were achieved in a two-step process. A soluble, low-molecular-weight PMS pre-polymer was formed via the polycondensation reaction between sebacic acid and D-mannitol. Nanocomposites with different CNC content were prepared by solution-casting and curing under vacuum using two different profiles designed to prepare materials with low and high degree of crosslinking. The as-prepared nanocomposites have higher stiffness and toughness than the neat PMS matrix while maintaining a high elongation at break. A highly crosslinked nanocomposite with a CNC content of 5 wt % displays a sixfold increase in Young’s modulus and a fivefold improvement in toughness. Nanocomposites also exhibit a shape memory effect with a switch temperature in the range of 15 to 45 C; in particular the materials with a thermal transition in the upper part of this range are potentially useful for biomedical applications | URI: | http://hdl.handle.net/10261/115764 | Identificadores: | issn: 0887-624X e-issn: 1099-0518 |
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