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Catalytic enantioselective hydrophosphonylation of aldehydes and imines

AutorMerino, Pedro ; Marqués-López, Eugenia ; Herrera, Raquel P.
Palabras claveHydrophosphonylation
Asymmetric catalysis
α-hydroxyphosphonates
Organocatalysis
Phospho-aldol reaction
α-aminophosphonates
Fecha de publicación2008
EditorJohn Wiley & Sons
CitaciónAdvanced Synthesis and Catalysis 350(9): 1195-1208 (2008)
ResumenIn this review, recent advances in catalytic asymmetric hydrophosphonylation of aldehydes and imines are discussed. We also summarize several proposed mechanisms for the different possibilities of asymmetric induction and the application of this catalytic methodology to the enantioselective synthesis of α-amino and α-hydroxy phosphonates. A variety of metal-based chiral catalysts as well as several organic catalysts have been exploited as suitable systems for the preparation of enantiomerically pure phosphonates. The recent evolution and future trends of those and other catalytic systems are described.
URIhttp://hdl.handle.net/10261/114023
DOI10.1002/adsc.200800131
Identificadoresdoi: 10.1002/adsc.200800131
issn: 1615-4150
e-issn: 1615-4169
Aparece en las colecciones: (ICMA) Artículos
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