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Título: | Catalytic enantioselective hydrophosphonylation of aldehydes and imines |
Autor: | Merino, Pedro CSIC ORCID ; Marqués-López, Eugenia CSIC ORCID; Herrera, Raquel P. CSIC ORCID | Palabras clave: | Hydrophosphonylation Asymmetric catalysis α-hydroxyphosphonates Organocatalysis Phospho-aldol reaction α-aminophosphonates |
Fecha de publicación: | 2008 | Editor: | John Wiley & Sons | Citación: | Advanced Synthesis and Catalysis 350(9): 1195-1208 (2008) | Resumen: | In this review, recent advances in catalytic asymmetric hydrophosphonylation of aldehydes and imines are discussed. We also summarize several proposed mechanisms for the different possibilities of asymmetric induction and the application of this catalytic methodology to the enantioselective synthesis of α-amino and α-hydroxy phosphonates. A variety of metal-based chiral catalysts as well as several organic catalysts have been exploited as suitable systems for the preparation of enantiomerically pure phosphonates. The recent evolution and future trends of those and other catalytic systems are described. | URI: | http://hdl.handle.net/10261/114023 | DOI: | 10.1002/adsc.200800131 | Identificadores: | doi: 10.1002/adsc.200800131 issn: 1615-4150 e-issn: 1615-4169 |
Aparece en las colecciones: | (ICMA) Artículos |
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accesoRestringido.pdf | 15,38 kB | Adobe PDF | Visualizar/Abrir |
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