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Metal-free [3+2] cycloaddition of azides with Tf2CCH2 for the regioselective preparation of elusive 4-(trifluoromethylsulfonyl)-1,2,3-triazoles

AuthorsAlcaide, Benito ; Almendros, Pedro ; Lázaro-Milla, C.
Issue Date2015
PublisherRoyal Society of Chemistry (UK)
CitationChemical Communications 51: 6992-6995 (2015)
Abstract1,2-Dipole Tf2CCH2 is generated in situ and immediately reacts at room temperature with an azide to afford previously unknown 4-trifluoromethanesulfonyl 1,2,3-triazoles through a stepwise [3+2] cycloaddition reaction. Noteworthily, this mild and powerful uncatalyzed protocol is highly regio- and chemoselective. This journal is
Identifiersdoi: 10.1039/c5cc01223f
issn: 1359-7345
e-issn: 1364-548X
Appears in Collections:(IQOG) Artículos
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