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Title

Crossed intramolecular Rauhut−Currier-type reactions via dienamine activation

AuthorsMarqués-López, Eugenia ; Herrera, Raquel P.; Marks, Timo; Jacobs, Wiebke C.; Könning, Daniel; Figueiredo, Renata M. de; Christmann, Mathias
Issue Date2009
PublisherAmerican Chemical Society
CitationOrganic Letters 11(18): 4116-4119 (2009)
AbstractThe intramolecular Rauhut−Currier reaction creates a carbon−carbon bond between two tethered Michael acceptors. Previous asymmetric versions have relied on 1,4-additions of chiral nucleophilic catalysts. Herein, we investigate a novel strategy that involves the formation of electron rich dienamines as key intermediates. Our methodology provides an efficient entry to the iridoid framework.
DescriptionTrabajo presentado como póster al 3.Tag der Chemie celebrado en Dortmund (Alemania) en 2010.
Publisher version (URL)http://dx.doi.org/10.1021/ol901614t
URIhttp://hdl.handle.net/10261/113980
DOI10.1021/ol901614t
Identifiersdoi: 10.1021/ol901614t
issn: 1523-7060
e-issn: 1523-7052
Appears in Collections:(ICMA) Artículos
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