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Título

Diarylprolinol derivatives in organocatalysis from another point of view: structural aspects

Autor Marqués-López, Eugenia ; Herrera, Raquel P.
Palabras clave Metal-based catalysis
Organocatalyst
Additive
Mechanism
α,α-diarylprolinol silyl ether
Catalysis
Organocatalysis
α,α-diaryl-2-pyrrolidinemethanol
Fecha de publicación 2011
EditorBentham Science Publishers
Citación Current Organic Chemistry 15(13): 2311-2327 (2011)
ResumenThe synthesis of complex active molecules has afforded the search for new methods and new processes in organic synthesis. In this context, organic metal free catalysis has appeared as a powerful tool being complementary to metal catalysis in the field of asymmetric synthesis. The success of this methodology has been increasing in the last decade and the research for new organocatalytic systems as well as new applications has attracted the interest of many research groups. Among all organocatalysts, diarylprolinol derivatives have emerged as powerful scaffolds for asymmetric catalysis, proof of that is the huge number of publications reported using this kind of structure as catalysts. However, only in a few cases, different aspects of the catalysts structures and additional additives have been largely studied and a plausible explanation has been given. In this sense, this review treats to illustrate these important and scarce examples and to give a very general vision relating to the application of diarylprolinol derivatives in organocatalytic transformations from another point of view: structural aspects. The influence of catalyst structure, electronic effects, and the use of additives will be the aim of discussion and comment in this work.
Versión del editorhttp://dx.doi.org/10.2174/138527211796150705
URI http://hdl.handle.net/10261/113968
DOI10.2174/138527211796150705
Identificadoresdoi: 10.2174/138527211796150705
issn: 1385-2728
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