Synthesis of highly functionalized enantiopure halocyclopropanes derived from carbohydrates

Por favor, use este identificador para citar o enlazar a este item: http://hdl.handle.net/10261/112933

COMPARTIR / EXPORTAR:

SHARE CORE BASE	Comparte tu historia de Acceso Abierto
Visualizar otros formatos: MARC \| Dublin Core \| RDF \| ORE \| MODS \| METS \| DIDL \| DATACITE
Refman EndNote Bibtex RefWorks Excel CSV PDF DataCite Send via email

Título:	Synthesis of highly functionalized enantiopure halocyclopropanes derived from carbohydrates
Autor:	Rodríguez-Solla, Humberto; Concellón, Carmen; Amo, Vicente del; Díaz-Pardo, Ainhoa; Blanco, Elena G.; García-Granda, Santiago CSIC ORCID ; Díaz, M. Rosario CSIC; Llavona, Ricardo; Soengas, Raquel G.
Palabras clave:	Carbohydrates Amides Carbenoids Chromium Small ring systems
Fecha de publicación:	2013
Editor:	Wiley-VCH
Citación:	European Journal of Organic Chemistry (22): 4953-4961 (2013)
Resumen:	A chromium-mediated synthesis of enantiopure sugar-based halocyclopropanecarboxamides is reported. This reaction can be stereospecifically carried out on (E)- or (Z)-¿,ß-unsaturated amides and takes place with the formation of a new C-Hal stereogenic center, which is generated with total stereoselectivity. Synthetic applications of the obtained halocyclopropanecarboxamides are also reported. The structure of the halocyclopropanes and derivatives were established by X-ray analysis. A mechanism to explain these transformations is proposed. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
URI:	http://hdl.handle.net/10261/112933
DOI:	10.1002/ejoc.201300322
Identificadores:	doi: 10.1002/ejoc.201300322 issn: 1434-193X e-issn: 1099-0690
Aparece en las colecciones:	(CINN) Artículos

Fichero	Descripción	Tamaño	Formato
accesoRestringido.pdf		15,38 kB	Adobe PDF	Visualizar/Abrir

CORE Recommender

3

checked on 24-abr-2024

3

checked on 25-feb-2024

288

checked on 23-abr-2024

86

checked on 23-abr-2024

Check