English   español  
Please use this identifier to cite or link to this item: http://hdl.handle.net/10261/112140
logo share SHARE   Add this article to your Mendeley library MendeleyBASE

Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL | DATACITE
Exportar a otros formatos:

DC FieldValueLanguage
dc.contributor.authorLara Castells, María Pilar de-
dc.contributor.authorStoll, H.-
dc.contributor.authorCivalleri, B.-
dc.contributor.authorCausà, M. Voloshina, E.-
dc.contributor.authorMitrushchenkov, Alexander O.-
dc.contributor.authorPi, Martí-
dc.identifierdoi: 10.1063/1.4898430-
dc.identifierissn: 0021-9606-
dc.identifier.citationJournal of Chemical Physics 141: 151102 (2014)-
dc.description5 pags.; 2 figs.; 2 tabs.-
dc.description.abstractIn this work we propose a general strategy to calculate accurate He-surface interaction potentials. It extends the dispersionless density functional (dlDF) approach recently developed by Pernal et al. [Phys. Rev. Lett. 109, 263201 (2009)] to adsorbate-surface interactions by including periodic boundary conditions. We also introduce a scheme to parametrize the dispersion interaction by calculating two- and three-body dispersion terms at CCSD(T) level via the method of increments [Stoll, J. Chem. Phys. 97, 8449 (1992)]. The performance of the composite approach is tested on 4He/graphene by determining the energies of the low-lying selective adsorption states, finding an excellent agreement with the best available theoretical data. Second, the capability of the approach to describe dispersionless correlation effects realistically is used to extract dispersion effects in time-dependent density functional simulations on the collision of 4He droplets with a single graphene sheet. It is found that dispersion effects play a key role in the fast spreading of the 4He nanodroplet, the evaporation-like process of helium atoms, and the formation of solid-like helium structures. These characteristics are expected to be quite general and highly relevant to explain experimental measurements with the newly developed helium droplet mediated deposition technique. © 2014 AIP Publishing LLC-
dc.description.sponsorshipThis work has been supported by Grants Nos. CCG08-CSIC/ESP-3680 from CSIC-CM, FIS2011-29596-C02-01 and FIS2011-28617- C02-01 from DGI, Spain (FEDER), and 2009SGR1289 from Generatitat de Catalunya.-
dc.publisherAmerican Institute of Physics-
dc.subjectHelium droplets-
dc.subjectHelium-surface interaction-
dc.subjectNuclear timedependent density functional theory-
dc.subjectDispersionless density functional theory-
dc.titleCommunication: A Combined Periodic Density Functional and Incremental Wave-Function-based Approach for the Dispersion-Accounting Time-Resolved Dynamics of 4He Nanodroplets on Surfaces: 4He/Graphene-
dc.description.versionPeer Reviewed-
Appears in Collections:(CFMAC-IFF) Artículos
Files in This Item:
File Description SizeFormat 
Communication.pdf389,68 kBAdobe PDFThumbnail
Show simple item record

WARNING: Items in Digital.CSIC are protected by copyright, with all rights reserved, unless otherwise indicated.