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http://hdl.handle.net/10261/111951
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Campo DC | Valor | Lengua/Idioma |
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dc.contributor.author | Torre, María C. de la | - |
dc.contributor.author | Asenjo, María | - |
dc.contributor.author | Ramírez-López, Pedro | - |
dc.contributor.author | Sierra, Miguel A. | - |
dc.date.accessioned | 2015-03-06T11:00:12Z | - |
dc.date.available | 2015-03-06T11:00:12Z | - |
dc.date.issued | 2015 | - |
dc.identifier | doi: 10.1002/ejoc.201403541 | - |
dc.identifier | issn: 1434-193X | - |
dc.identifier | e-issn: 1099-0690 | - |
dc.identifier.citation | European Journal of Organic Chemistry 2015: 1054-1067 (2015) | - |
dc.identifier.uri | http://hdl.handle.net/10261/111951 | - |
dc.description.abstract | Two different approaches to highly symmetric macrocycles by reversible Nicholas reactions have been developed. The first sequence uses a bis[Co2(CO)6] complex derived from a double propargylic alcohol supporting two natural product moieties. The reactions with BF3·OEt2 and different benzene dimethanols yielded either (1:1) or (2:2) adducts, depending essentially on the nature of the tether joining both Co clusters. Alternatively, the Nicholas reactions of Co-complexed propargyl alcohol templates with one steroid and one monoterpene fragment as well as one aromatic terminus containing an alcohol moiety yielded the corresponding macrocycles derived from self-dimerization. Both routes to macrocycles are complementary and efficiently produce sophisticated natural-product-containing structures. | - |
dc.publisher | John Wiley & Sons | - |
dc.rights | closedAccess | - |
dc.subject | Steroids | - |
dc.subject | Cobalt | - |
dc.subject | Dynamic covalent chemistry | - |
dc.subject | Macrocycles | - |
dc.title | The reversible Nicholas reaction in the synthesis of highly symmetric natural-product-based macrocycles | - |
dc.type | artículo | - |
dc.identifier.doi | 10.1002/ejoc.201403541 | - |
dc.date.updated | 2015-03-06T11:00:12Z | - |
dc.description.version | Peer Reviewed | - |
dc.language.rfc3066 | eng | - |
dc.type.coar | http://purl.org/coar/resource_type/c_6501 | es_ES |
item.openairetype | artículo | - |
item.grantfulltext | none | - |
item.cerifentitytype | Publications | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.fulltext | No Fulltext | - |
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