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Coordination studies of the ferrocenyl phosphine selenide ligand FcCON(CH2CH2PPh2Se)2

AutorCanales, Silvia; Villacampa, M. Dolores ; Laguna, Antonio ; Gimeno, M. Concepción
Palabras claveGold compounds
Group 11 compounds
Phosphine selenide ligands
Amidephosphine ligands
Palladium compounds
Ferrocene derivatives
Fecha de publicación2014
EditorElsevier
CitaciónJournal of Organometallic Chemistry 760: 84-88 (2014)
ResumenThe oxidation of the ferrocenyl phosphine ligand FcCON(CH 2CH2PPh2)2 with elemental selenium leads to the synthesis of the ferrocenyl phosphine selenide FcCON(CH 2CH2PPh2Se)2 (L1). The coordination chemistry of this ligand with group 11 metals and palladium has been studied, and several complexes with coordination of the metal to the selenium atoms have been prepared. The ligand L1 reacts with pentafluorophenyl gold(I) or gold(III) species leading to the complexes [{Au(C6F5)} 2(μ-L1)] or [{Au(C6F5)3} 2(μ-L1)], respectively. The reaction of two equivalents of L1 with silver(I) or copper(I) salts gives the tetra-coordinate complexes [M(L1) 2]X (M = Cu, X = PF6; Ag, X = OTf), or with trans-[PdCl2(NCPh)2] affords the square planar palladium derivative [PdCL2(L1)]. The ligand L1 and the gold(I) complex [{Au(C6F5)}2(μ-L1)] have been characterized by X-ray diffraction. © 2013 Elsevier B.V. All rights reserved.
URIhttp://hdl.handle.net/10261/111810
DOI10.1016/j.jorganchem.2013.12.017
Identificadoresdoi: 10.1016/j.jorganchem.2013.12.017
issn: 0022-328X
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