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http://hdl.handle.net/10261/111659
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dc.contributor.author | Mena, Inmaculada | - |
dc.contributor.author | Casado, Miguel A. | - |
dc.contributor.author | Polo, Víctor | - |
dc.contributor.author | García-Orduña, Pilar | - |
dc.contributor.author | Lahoz, Fernando J. | - |
dc.contributor.author | Oro, Luis A. | - |
dc.date.accessioned | 2015-03-03T09:47:26Z | - |
dc.date.available | 2015-03-03T09:47:26Z | - |
dc.date.issued | 2014 | - |
dc.identifier | doi: 10.1039/C3DT52911H | - |
dc.identifier | issn: 1477-9226 | - |
dc.identifier | e-issn: 1477-9234 | - |
dc.identifier.citation | Dalton Transactions 43(4): 1609-1619 (2014) | - |
dc.identifier.uri | http://hdl.handle.net/10261/111659 | - |
dc.description.abstract | Selected secondary phosphanes (H-PR2; R = Ph, Cy, iPr) smoothly react with a parent amido-bridged diiridium cyclooctadiene complex affording mixed amido/(bis)phosphido dinuclear species. A careful investigation of the reaction profile, carried out by experimental and theoretical tools, revealed that, after an initial amido/phosphido exchange, at low temperatures a second molecule of secondary phosphane adds to the dinuclear system through an oxidative addition process leading to a hydrido amido/bis(phosphido) mixed-valence complex [IrIII/IrI]. These species rearrange above -10 °C into the most stable isomer that arises from a migration of the hydrido moiety to one of the CH fragments of a coordinated cod molecule, a transformation facilitated by the formation of an intermetallic bond. Further heating of these species reductively eliminates ammonia affording bis(phosphido)-metal-metal bonded complexes. This journal is © The Royal Society of Chemistry. | - |
dc.description.sponsorship | Financial support from the project CTQ2012-35665 and the CONSOLIDER INGENIO-2010 program under the projects MULTICAT (CSD2009-00050) and Factoría de Cristalización (CSD2006-0015), and DGA/FSE 07, is acknowledged. P.G.O. acknowledges the CSIC “JAE-Doc” program, cofunded by the ESF and Factoría de Cristalización projects, for financial support. | - |
dc.publisher | Royal Society of Chemistry (UK) | - |
dc.rights | closedAccess | - |
dc.title | P-H activation of secondary phosphanes on a parent amido diiridium complex | - |
dc.type | artículo | - |
dc.identifier.doi | 10.1039/C3DT52911H | - |
dc.date.updated | 2015-03-03T09:47:26Z | - |
dc.description.version | Peer Reviewed | - |
dc.language.rfc3066 | eng | - |
dc.contributor.funder | Factoría Española de Cristalización | - |
dc.contributor.funder | Diputación General de Aragón | - |
dc.contributor.funder | Ministerio de Economía y Competitividad (España) | - |
dc.contributor.funder | Consejo Superior de Investigaciones Científicas (España) | - |
dc.contributor.funder | European Commission | - |
dc.relation.csic | Sí | - |
dc.identifier.funder | http://dx.doi.org/10.13039/501100003329 | es_ES |
dc.identifier.funder | http://dx.doi.org/10.13039/501100003339 | es_ES |
dc.identifier.funder | http://dx.doi.org/10.13039/501100000780 | es_ES |
dc.type.coar | http://purl.org/coar/resource_type/c_6501 | es_ES |
item.openairetype | artículo | - |
item.cerifentitytype | Publications | - |
item.grantfulltext | none | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.fulltext | No Fulltext | - |
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