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Title

Crystallization, phase evolution and corrosion of Fe-based metallic glasses: An atomic-scale structural and chemical characterization study

AuthorsDuarte, M.J.; Kostka, A.; Jiménez, José Antonio; Choi, P.; Klemm, J.; Crespo, D.; Raabe, D.; Rennert, F.U.
KeywordsAtom probe tomography
Transmission electron microscopy
Phase evolution
Crystallization
Metallic glasses
Issue Date2014
PublisherElsevier
CitationActa Materialia 71: 20-30 (2014)
AbstractUnderstanding phase changes, including their formation and evolution, is critical for the performance of functional as well as structural materials. We analyze in detail microstructural and chemical transformations of the amorphous steel Fe50Cr15Mo14C15B6 during isothermal treatments at temperatures ranging from 550 to 800 °C. By combining high-resolution transmission electron microscopy and Rietveld analyses of X-ray diffraction patterns together with the local chemical data obtained by atom probe tomography, this research provides relevant information at the atomic scale about the mechanisms of crystallization and the subsequent phases evolution. During the initial stages of crystallization a stable (Fe,Cr) 23(C,B)6 precipitates as well as two metastable intermediates of M3(C,B) and the intermetallic χ-phase. When full crystallization is reached, only a percolated nano-scale Cr-rich (Fe,Cr) 23(C,B)6 and Mo-rich η-Fe3Mo3C structure is detected, with no evidence to suggest that other phases appear at any subsequent time. Finally, the corrosion behavior of the developed phases is discussed from considerations of the obtained atomic information. © 2014 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.
URIhttp://hdl.handle.net/10261/111647
DOI10.1016/j.actamat.2014.02.027
Identifiersdoi: 10.1016/j.actamat.2014.02.027
issn: 1359-6454
Appears in Collections:(CENIM) Artículos
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