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Título: | A comparative study of structural patterns and luminescent properties of silver-DAFO complexes with carborane- versus "classical"-diphosphanes |
Autor: | Crespo, Olga CSIC ORCID; Gimeno, M. Concepción CSIC ORCID; Laguna, Antonio CSIC ORCID; Marriott, Rosie; Sáez-Rocher, José M. CSIC; Villacampa, M. Dolores CSIC | Fecha de publicación: | 2014 | Editor: | Royal Society of Chemistry (UK) | Citación: | Dalton Transactions 43(32): 12214-12220 (2014) | Resumen: | New complexes with the DAFO (4,5-diazafluoren-9-one) ligand of stoichiometry [Ag(DAFO)(P-P)]OTf [P-P = dppe, 1,2-bis(diphenylphosphane)ethane; dppp, 1,3-bis(diphenylphosphane)propane; dppph, ortho-bis(diphenylphosphane) benzene; dppcc, 1,2-bis(diphenylphosphane)-1,2-dicarba-closo-dodecaborane; dipcc, 1,2-bis(diisopropylphosphane)-1,2-dicarba-nido-dodecaborane], [Ag(DAFO)(P-P*)] [P-P* = dppnc, 7,8-bis(diphenylphosphane)-7,8- dicarba-nido-undecaborate(-1); dipnc, 7,8-bis(diisopropylphosphane)-7,8-dicarba- closo-undecaborate(-1)] and [Ag(DAFO)(OTf)L] [L = PPh3; dpccMe, 1-diphenylphosphane-2-methyl-1,2-dicarba-closo-dodecaborane] are reported. The structures of the complexes depend on the skeleton of the diphosphane. Most of these compounds are luminescent and their emissions seem to have originated from IL (DAFO) transitions, modified upon coordination to silver. © 2014 the Partner Organisations. | URI: | http://hdl.handle.net/10261/111565 | DOI: | 10.1039/C4DT00797B | Identificadores: | doi: 10.1039/C4DT00797B issn: 1477-9226 e-issn: 1477-9234 |
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