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Solvent-induced lone pair activity tuning and vapoluminescence in a Pt2Pb cluster

AuthorsBerenguer, Jesús R.; Lalinde, Elena; Martín, Antonio ; Moreno, M. Teresa; Ruiz, Santiago; Sánchez, Sergio ; Shahsavari, Hamid R.
Issue Date2013
PublisherRoyal Society of Chemistry (UK)
CitationChemical Communications 49(44): 5067-5069 (2013)
AbstractWe report a novel cluster, [{Pt(C6F5)(bzq)} 2Pb(Spy)2] 1, that displays reversible vapoluminescence to specific organic vapours; this behaviour can be related to the stereochemical activity of the lone pair around the PbII in the ground state and to the distinct distortion of the coordination environment (1 and 1-solvent) upon photoexcitation. This journal is © The Royal Society of Chemistry 2013.
Publisher version (URL)http://dx.doi.org/10.1039/C3CC41638K
Identifiersdoi: 10.1039/C3CC41638K
issn: 1359-7345
e-issn: 1364-548X
Appears in Collections:(ISQCH) Artículos
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