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Title

Proton-conducting supramolecular metallogels from the lowest molecular weight assembler ligand: A quote for simplicity

AuthorsSaha, Subhadeep; Schön, Eva-Maria; Cativiela, Carlos ; Díaz Díaz, David ; Banerjee, Rahul
KeywordsCopper
Supramolecular chemistry
Metallogels
Proton conductivity
Low-molecular-weight ligands
Issue Date2013
PublisherWiley-VCH
CitationChemistry - A European Journal 19(29): 9562-9568 (2013)
AbstractOxalic acid has been proven to be the lowest molecular weight organic ligand able to form robust supramolecular metallogel networks in the presence of metal salts. In particular, two novel multifunctional metallogels were readily prepared at room temperature by simple mixing of stock solutions of Cu II acetate monohydrate or CuII perchlorate hexahydrate and oxalic acid dihydrate. Formation of different polymorphs and unprecedented proton conduction under anhydrous conditions were also demonstrated with some of these materials.
URIhttp://hdl.handle.net/10261/111373
DOI10.1002/chem.201204542
Identifiersdoi: 10.1002/chem.201204542
issn: 0947-6539
e-issn: 1521-3765
Appears in Collections:(ISQCH) Artículos
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