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Proton cascade in a molecular solid: H/D exchange on mobile and immobile water

AuthorsCapelli, Silvia C.; Falvello, Larry R.; Forcén-Vázquez, E.; McIntyre, G. J.; Palacio, Fernando; Sanz, Sergio; Tomás, Milagros
KeywordsHydrogen transfer
Coordination chemistry
X-ray diffraction
Neutron diffraction
Hydrogen bonds
Issue Date2013
CitationAngewandte Chemie - International Edition 52(50): 13463-13467 (2013)
AbstractWorking without pores: In non-porous, channel-free crystals of a manganese citrate coordination polymer, neutron diffraction reveals that the water molecules, both metal-bound and co-crystallized, undergo full hydrogen/deuterium exchange. Neutron diffraction analyses show a pattern of hydrogen disorder that can be interpreted in terms of the Grotthuss proton-cascade mechanism (see scheme). © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Identifiersdoi: 10.1002/anie.201307994
issn: 1433-7851
e-issn: 1521-3773
Appears in Collections:(ICMA) Artículos
(ISQCH) Artículos
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