An insight into Faradaic phenomena in activated carbon investigated by means of the microelectrode technique

Abstract

Cyclic voltammetry was performed on activated carbon particles in a microelectrode setup to investigate the behaviour of an activated carbon with oxygen functionalities. Quinoid type redox peaks were clearly seen in the potential region around −0.5 V vs. Hg/HgO. After polarization below −0.4 V, an anodic peak confirms previous studies using a pristine carbon, but in the present work much higher in intensity. In addition, a corresponding cathodic peak, not previously reported, was also found. The appearance of this pair of peaks in a functionalized carbon may be connected to reversible hydrogen adsorption together with Faradaic reactions involving oxygenated functional groups.