English   español  
Please use this identifier to cite or link to this item: http://hdl.handle.net/10261/111260
logo share SHARE logo core CORE   Add this article to your Mendeley library MendeleyBASE

Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL
Exportar a otros formatos:


N-heterocyclic carbene ligands as modulators of luminescence in three-coordinate gold(I) complexes with spectacular quantum yields

AuthorsVisbal, Renso ; Ospino, Isaura; López-de-Luzuriaga, José M.; Laguna, Antonio ; Gimeno, M. Concepción
Issue Date2013
PublisherAmerican Chemical Society
CitationJournal of the American Chemical Society 135(12): 4712-4715 (2013)
AbstractThe first three-coordinate gold(I) N-heterocyclic carbene (NHC) complexes have been prepared with the nido-carborane diphosphine. The complexes are brightly luminescent and present very high quantum yield values. The carbene ligand is able to modulate the energy of the emissions and, depending upon the substituent, the luminescence changes from blue to green. Theoretical calculations corroborate that the emissions are phosphorescence and arise from charge transfer (LML′CT) transitions from nido-carborane ligand (L) to metal/ligand group >gold(I)-NHC ligand> (ML′). © 2013 American Chemical Society.
Identifiersdoi: 10.1021/ja401523x
issn: 0002-7863
e-issn: 1520-5126
Appears in Collections:(ISQCH) Artículos
Files in This Item:
File Description SizeFormat 
accesoRestringido.pdf15,38 kBAdobe PDFThumbnail
Show full item record
Review this work

Related articles:

WARNING: Items in Digital.CSIC are protected by copyright, with all rights reserved, unless otherwise indicated.