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dc.contributor.authorEsteruelas, Miguel A.-
dc.contributor.authorFernández, Israel-
dc.contributor.authorGómez-Gallego, Mar-
dc.contributor.authorMartín-Ortíz, Mamen-
dc.contributor.authorMolina, Pedro-
dc.contributor.authorOliván, Montserrat-
dc.contributor.authorOtón, Francisco-
dc.contributor.authorSierra, Miguel A.-
dc.contributor.authorValencia, Marta-
dc.date.accessioned2015-02-25T12:34:53Z-
dc.date.available2015-02-25T12:34:53Z-
dc.date.issued2013-
dc.identifierdoi: 10.1039/C2DT32548A-
dc.identifierissn: 1477-9226-
dc.identifiere-issn: 1477-9234-
dc.identifier.citationDalton Transactions 42(10): 3597-3608 (2013)-
dc.identifier.urihttp://hdl.handle.net/10261/111255-
dc.description.abstractThe efficient synthesis of mono- and dinuclear Os(iv) bipyridyl complexes is reported. These compounds show a two-step oxidation process leading to notable structural changes, which are reflected in their emission properties. During the second oxidation process a tetracation with a hydride-dihydrogen structure (instead of a trihydride) is formed. This results in a significant bathochromic shift of the emission band, accompanied by a moderate increase in intensity. This journal is © 2013 The Royal Society of Chemistry.-
dc.description.sponsorshipFinancial support from grants CTQ-2010-20414-C02-01/BQU (to MAS), CTQ2011-23459 (to MAE) and Consolider Ingenio 2010 (CSD2007-00006) from the MINECO, Diputación General de Aragón (E35), Comunidad de Madrid (P2009/PPQ1634-AVANCAT) (UCM group), and European Social Fund is acknowledged. I.F. and F.O. are Ramón y Cajal and Juan de la Cierva fellows, respectively. M.M.O is an FPI fellow.-
dc.publisherRoyal Society of Chemistry (UK)-
dc.relationS2009/PPQ-1634/AVANCAT-
dc.rightsclosedAccess-
dc.titleMono- and dinuclear osmium N,N′-di- and tetraphenylbipyridyls and extended bipyridyls. Synthesis, structure and electrochemistry-
dc.typeartículo-
dc.identifier.doi10.1039/C2DT32548A-
dc.date.updated2015-02-25T12:34:53Z-
dc.description.versionPeer Reviewed-
dc.language.rfc3066eng-
dc.contributor.funderComunidad de Madrid-
dc.contributor.funderMinisterio de Economía y Competitividad (España)-
dc.contributor.funderEuropean Commission-
dc.contributor.funderDiputación General de Aragón-
dc.contributor.funderConsejo Superior de Investigaciones Científicas (España)-
dc.relation.csic-
dc.identifier.funderhttp://dx.doi.org/10.13039/501100003329es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100000780es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100003339es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/100012818es_ES
dc.type.coarhttp://purl.org/coar/resource_type/c_6501es_ES
item.openairetypeartículo-
item.grantfulltextnone-
item.cerifentitytypePublications-
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
item.fulltextNo Fulltext-
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