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http://hdl.handle.net/10261/111255
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dc.contributor.author | Esteruelas, Miguel A. | - |
dc.contributor.author | Fernández, Israel | - |
dc.contributor.author | Gómez-Gallego, Mar | - |
dc.contributor.author | Martín-Ortíz, Mamen | - |
dc.contributor.author | Molina, Pedro | - |
dc.contributor.author | Oliván, Montserrat | - |
dc.contributor.author | Otón, Francisco | - |
dc.contributor.author | Sierra, Miguel A. | - |
dc.contributor.author | Valencia, Marta | - |
dc.date.accessioned | 2015-02-25T12:34:53Z | - |
dc.date.available | 2015-02-25T12:34:53Z | - |
dc.date.issued | 2013 | - |
dc.identifier | doi: 10.1039/C2DT32548A | - |
dc.identifier | issn: 1477-9226 | - |
dc.identifier | e-issn: 1477-9234 | - |
dc.identifier.citation | Dalton Transactions 42(10): 3597-3608 (2013) | - |
dc.identifier.uri | http://hdl.handle.net/10261/111255 | - |
dc.description.abstract | The efficient synthesis of mono- and dinuclear Os(iv) bipyridyl complexes is reported. These compounds show a two-step oxidation process leading to notable structural changes, which are reflected in their emission properties. During the second oxidation process a tetracation with a hydride-dihydrogen structure (instead of a trihydride) is formed. This results in a significant bathochromic shift of the emission band, accompanied by a moderate increase in intensity. This journal is © 2013 The Royal Society of Chemistry. | - |
dc.description.sponsorship | Financial support from grants CTQ-2010-20414-C02-01/BQU (to MAS), CTQ2011-23459 (to MAE) and Consolider Ingenio 2010 (CSD2007-00006) from the MINECO, Diputación General de Aragón (E35), Comunidad de Madrid (P2009/PPQ1634-AVANCAT) (UCM group), and European Social Fund is acknowledged. I.F. and F.O. are Ramón y Cajal and Juan de la Cierva fellows, respectively. M.M.O is an FPI fellow. | - |
dc.publisher | Royal Society of Chemistry (UK) | - |
dc.relation | S2009/PPQ-1634/AVANCAT | - |
dc.rights | closedAccess | - |
dc.title | Mono- and dinuclear osmium N,N′-di- and tetraphenylbipyridyls and extended bipyridyls. Synthesis, structure and electrochemistry | - |
dc.type | artículo | - |
dc.identifier.doi | 10.1039/C2DT32548A | - |
dc.date.updated | 2015-02-25T12:34:53Z | - |
dc.description.version | Peer Reviewed | - |
dc.language.rfc3066 | eng | - |
dc.contributor.funder | Comunidad de Madrid | - |
dc.contributor.funder | Ministerio de Economía y Competitividad (España) | - |
dc.contributor.funder | European Commission | - |
dc.contributor.funder | Diputación General de Aragón | - |
dc.contributor.funder | Consejo Superior de Investigaciones Científicas (España) | - |
dc.relation.csic | Sí | - |
dc.identifier.funder | http://dx.doi.org/10.13039/501100003329 | es_ES |
dc.identifier.funder | http://dx.doi.org/10.13039/501100000780 | es_ES |
dc.identifier.funder | http://dx.doi.org/10.13039/501100003339 | es_ES |
dc.identifier.funder | http://dx.doi.org/10.13039/100012818 | es_ES |
dc.type.coar | http://purl.org/coar/resource_type/c_6501 | es_ES |
item.openairetype | artículo | - |
item.grantfulltext | none | - |
item.cerifentitytype | Publications | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.fulltext | No Fulltext | - |
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