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Título: | Labile rhodium(I)-N-heterocyclic carbene complexes |
Autor: | Palacios, Laura CSIC; Giuseppe, Andrea di CSIC ORCID CVN; Opalinska, Anna; Castarlenas, Ricardo CSIC ORCID; Pérez-Torrente, Jesús J. CSIC ORCID; Lahoz, Fernando J. CSIC ORCID; Oro, Luis A. CSIC ORCID | Fecha de publicación: | 2013 | Editor: | American Chemical Society | Citación: | Organometallics 32(9): 2768-2774 (2013) | Resumen: | The neutral square-planar complexes Rh(acac)(IPr)(η2-olefin) have been prepared from [Rh(μ-Cl)(IPr)(η2-olefin)]2 (IPr = 1,3-bis-(2,6-diisopropylphenyl)imidazol-2-carbene; olefin = cyclooctene, ethylene) and sodium acetylacetonate (acac). Protonation of the acetylacetonato complexes with triflic acid opens the way to the formation of the putative bare [Rh-IPr]+ fragment that has been stabilized at low temperature by labile ligands such as triflate, cyclooctene, and acetonitrile to generate Rh(OTf)(IPr)(η2-coe), [Rh(IPr)(η2-coe)(NCCH3)2]OTf, and [Rh(IPr)(NCCH3)3]OTf complexes. The derivative [Rh(IPr)(η2-coe)(NCCH3)2]OTf was further characterized by an X-ray diffraction analysis. | Versión del editor: | http://dx.doi.org/10.1021/om400209m | URI: | http://hdl.handle.net/10261/111238 | DOI: | 10.1021/om400209m | Identificadores: | doi: 10.1021/om400209m issn: 0276-7333 e-issn: 1520-6041 |
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Labile Rhodium(I)N-Heterocyclic Carbene Complexes.pdf | 657,26 kB | Adobe PDF | Visualizar/Abrir |
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