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Title

Imidazole-nitrile or imidazole-isonitrile C-C coupling on rhenium tricarbonyl complexes

AuthorsEspinal Viguri, Maialen; Huertos, Miguel A.; Pérez, Julio ; Riera, Lucía
KeywordsRhenium
CC coupling
Isonitrile ligands
Organometallic compounds
Imidazole
Issue Date2013
PublisherWiley-VCH
CitationChemistry - A European Journal 19(39): 12974-12977 (2013)
AbstractLigand activation: Deprotonation of the nitrile or isonitrile complexes [Re(CO)3(N-RIm)2(L)]+ (N-RIm=N-alkylimidazole; L=Nï£CtBu, Cï£NtBu) selectively afforded alkylidenamido or iminoacyl derivatives, respectively, in which C-C coupling has occurred. Protonation of the latter complex leads to aminocarbene products. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
URIhttp://hdl.handle.net/10261/111228
DOIhttp://dx.doi.org/10.1002/chem.201302303
Identifiersdoi: 10.1002/chem.201302303
issn: 0947-6539
e-issn: 1521-3765
Appears in Collections:(ISQCH) Artículos
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