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Heterolytic H2 activation on a carbene-ligated rhodathiaborane promoted by isonido-nido cage opening

AuthorsCalvo, Beatriz ; Macías, Ramón ; Polo, Víctor; Artigas, María José ; Lahoz, Fernando J. ; Oro, Luis A.
Issue Date2013
PublisherRoyal Society of Chemistry (UK)
CitationChemical Communications 49(84): 9863-9865 (2013)
AbstractA new mechanism of H2 activation is reported to occur on a carbene-ligated rhodathiaborane that features metal-thiaborane bifunctional synergistic effects. The key is the creation of vacant coordination sites by an isonido-nido structural transformation leading to the heterolytic H-H bond splitting. © 2013 The Royal Society of Chemistry.
Publisher version (URL)http://dx.doi.org/10.1039/C3CC45880F
Identifiersdoi: 10.1039/C3CC45880F
issn: 1359-7345
e-issn: 1364-548X
Appears in Collections:(ISQCH) Artículos
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