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Title

6,6'-(1E,1'E)-((1R,2R)-1,2-Diphenylethane-1,2-diyl)bis(azan-1-yl-1-ylidene)bis(methan-1-yl-1-ylidene)bis(2-tert-butyl-4-((trimethylsilyl)ethynyl)phenol)

AuthorsHuber, Thimo; Niehues, Lennart; Cativiela, Carlos ; Finn, Meghan G.; Díaz Díaz, David
KeywordsSalen ligands
Chiral 1,2-diamines
Alkynes
Nucleophilic addition
Issue Date2013
PublisherMultidisciplinary Digital Publishing Institute
CitationMolbank 1: M795 (2013)
AbstractFunctionalizable salen derivative, 6,6'-(1E,1'E)-((1R,2R)-1,2-diphenylethane-1,2-diyl)bis(azan-1-yl-1-ylidene)bis(methan-1-yl-1-ylidene)bis(2-tert-butyl-4-((trimethylsilyl) ethyn-yl)phenol) (3), was synthesized by condensation between (1R,2R)-1,2-diphenylethane-1,2-diamine (2) and 3-tert-butyl-2-hydroxy-5-((trimethylsilyl)ethynyl) benzaldehyde (1) under refluxing conditions. The title compound was characterized by 1H-NMR, 13C-NMR, FT-IR, high-resolution mass spectrometry, optical rotation and melting point determination.
DescriptionThis article is an open access article distributed under the terms and conditions of the Creative Commons Attribution license.
Publisher version (URL)http://dx.doi.org/10.3390/M795
URIhttp://hdl.handle.net/10261/111092
DOI10.3390/M795
ISSN1422-8599
Appears in Collections:(ISQCH) Artículos
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