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Synthesis, characterization and hydrolytic degradation of polyester-urethanes obtained by lipase biocatalysis

AutorBarrera-Rivera, Karla A.; Peponi, Laura ; Marcos-Fernández, Ángel ; Kenny, José María ; Martínez-Richa, Antonio
Palabras claveRing-opening polymerization
Lipase biocatalysis
Yarrowia lipolytica lipase
Degradable polyurethanes
Fecha de publicación2014
EditorElsevier
CitaciónPolymer Degradation and Stability 108: 188-194 (2014)
ResumenThe enzymatic synthesis of ¿¿¿-telechelic polycaprolactone diols (HOPCLOH) and block copolymers was studied. Synthesis of ¿¿¿-telechelic PCL diols was carried out by enzymatic ring opening polymerization with Yarrowia lipolytica lipase immobilized on Lewatit VP OC K2629 and Amberlyst 15, and using ethylene glycol, diethylene glycol and polyethylene glycol as initiators. Biodegradable linear polyester-urethanes were prepared from synthesized PCL diols and hexamethylenediisocyanate (HDI). Polyester-urethanes degradation was studied using thermogravimetric analysis (TGA) and hydrolysis (alkaline, acidic and neutral). It was found that content of ether linkages influences the thermal stability and hydrolytic degradation behavior of the analyzed polyurethanes. Hydrolytic degradation proceeds faster in alkaline media, in agreement with the expected susceptibility of ester COO¿ bonds to degradation in the polyester urethanes.
URIhttp://hdl.handle.net/10261/110093
DOI10.1016/j.polymdegradstab.2014.04.004
Identificadoresdoi: 10.1016/j.polymdegradstab.2014.04.004
issn: 0141-3910
e-issn: 1873-2321
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